Product ID:PRO-LINE #37-THINNER
MSDS Date:12/15/1992
FSC:8010
NIIN:00N048057
MSDS Number: BTYLC

PRO-LINE PAINT COMPANY

2646 MAIN ST
SAN DIEGO, CA 92113-3697
US

Emergency Phone: 619-728-3192;619-488-8364

Info Phone: 619-231-2313;619-232-8968

Cage: 9D157

PRO-LINE PAINT CO

SAN DIEGO, CA 92113-3697 US

Telephone: 619-231-2313; 619-232-8968

Cage: 9D157

BUTANE, 1,2-EPOXY-; (1,2-BUTYLENE OXIDE)

CAS: 106-88-7

RTECS: EK3675000

Fraction By Weight: 0.5%

OSHA PEL N/K

ACGIH TLV: N/K

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

METHANE, DIMETHOXY-; (DIMETHOXYMETHANE)

CAS: 109-87-5

RTECS: PA8750000

Fraction By Weight: 1.9%

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G.,

RTECS: 9999999ZZ

LIFE-SUSTAINING USES IN HUMANS ACUTELY OR

RTECS: 9999999ZZ

ARC WELD, OPEN FLAMES/HOT SURF. HEAT &/OR UV

RTECS: 9999999ZZ

USING IN CONFINED AREA, USE NIOSH/MSHA APPROVED

RTECS: 9999999ZZ

ETHANE,1,1,1-TRICHLORO-; (AROTHENE(R) TT SOLVENT CONTAINING

CAS: 71-55-6

RTECS: KJ2975000

Fraction By Weight: 100%

OSHA PEL 350 PPM;450 STEL

ACGIH TLV: 350 PPM;450 STEL

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

TERT-BUTYL ALCOHOL

CAS: 75-65-0

RTECS: EO1925000

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: NAUS, DIZZ, HDCH, & CONVULS.
CHRONIC: NOT APPLIC. INHAL: MAJOR RTE OF EXPOS, LOW SYSTEMIC TOX;
ACUTE IN 1000 PPM RANGE CAUSE NARCOS. OVEREXP CAN CAUSE DIZZ,
DRUNKENESS, & DROW, UNCON & EVEN DEA TH. SKIN/EYES: BURNING
SENSATION FROM VAP/LIQ. DERM, SENSIT, NO CORNEAL INJURY LIKELY. MAY
CAUSE CONJ. (EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:ABBSORBED THRU SKIN: PRLNGD/RPTD SKIN
CONT CAN CAUSE DEFAT. ABSORP THRU SKIN IS NOT A SIGNIFICANT RTE OF
EXPOS. INGEST: CAN CAUSE BURNING SENSATION, VOMIT, DIARR, DROW.
INGEST OF SM QTY IS NO T LIKELY TO BE TOX. REPORTS HAVE ASSOC RPTD
& PRLNGD OCCUP OVEREXP TO SOLV CAN CAUSE PERM BRAIN & NERV SYS DAM.
(SUPDAT)
Medical Cond Aggravated by Exposure:ASTHMA AND SKIN ALLERGIES.

First Aid:EYE:FLUSH IMMED W/FRESH WATER FOR @ LST 15 MIN BY AN EYE WASH
APPARATUS/BY HAND. SEEK MED ATTN. SKIN:WASH IMMED W/WATER. THEN
WASH W/SOAP & WATER, RINSE IMMED. SEEK MED ATTN. INHAL:MOVE TO
FRESH AIR; ARTF RESP IF NEC. SEEK MED ATTN. INGEST: SEEK MED ATTN.
DO NOT INDUCE VOMIT. RECOM TO MD: IN ACUTE CASES SEEK MED ATTN
IMMED. FOR WORKERS WHO MAY BE EXPOSED REGULARLY, PROVIDE DETAILED
PERIODIC EXAMS.

Flash Point Method:TCC
Flash Point:NONE
Lower Limits:7.3%@28C
Upper Limits:13%@28C
Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.
Fire Fighting Procedures:NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL
PROT EQUIP. BLANKET FLAME W/ONE OF ABOVE. VAPS OF COMBUST MAY BE
IRRITATING TO RESP TRACT. MAY CAUSE (SUPDAT)
Unusual Fire/Explosion Hazard:KEEP MATL AWAY FROM HEAT, SPARKS, & OPEN
FLAMES. EXPOSURE TO EXTREME FIRE CAN CAUSE EMISSION OF PHOSGENE.
THERMAL DECOMP PROD MAY INCL HCL AND PHOSGENE .

Spill Release Procedures:REMOVE ALL TYPES OF IGNITION SOURCES. PROVIDE
SUFFICIENT VENT. PROTECT CLEAN-UP PERSON W/NIOSH/MSHA APPRVD 8540
3M CORP RESP & GOGGLES.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:PROTECT AGAINST PHYSICAL DAM TO CONTRS
& SPILLAGE. STORE IN A COOL WELL VENTD AREA W/SPRINKLER SYS. KEEP
AWAY FROM HEAT. POST NO SMOKING SIGNS.
Other Precautions:USE W/ADEQ VENT. CAUTION: WHEN PROD IS RECEIVED IN A
55 GAL DRUM, DO NOT CUT INTO EMPTY DRUM W/ACETYLENE TORCH/ALLOW ANY
OPEN FLAMES NEAR DRUM UNLESS DRUM IS CLEANED & PURGED. NO SMOKING
IN AREA OF US E. DO NOT USE IN GEN VICIN OF (ING 7)

Respiratory Protection:USE NIOSH/MSHA APRVD DUST/MIST RESP (HIGH
EFFICINCY CARTRIDGES ADVISED) IF SPRAYING/SANDING. USE NIOSH/MSHA
APPRVD ORG VAP CARTRIDGE RESP IF TLV FOR SOLV COMPONENTS MAY BE
EXCEEDED E.G. 8540 3M CORP R ESP, (NIOSH/MSHA APPRVD). WHEN (ING 8)
Ventilation:USE LOCAL EXHAUST WHEN APPLYING THIS PAINT IN CONFINED
AREAS. KEEP VAPORS BELOW TLV.
Protective Gloves:SOLVENT RESISTANT GLOVES.
Eye Protection:GOGGLES W/SIDE SHIELDS.
Other Protective Equipment:USE PROT CLTHG & CHANGE CONTAMD CLTHG IMMED.
PROVIDE EMER SHOWERS & EYEWASH @ STATIONARY PAINT APPLICATN
FACILITIES.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
FIRE FIGHT PROC: BRTHG DFCLTYS PVNT HUMAN EXPOS TO FIRE, SMOKE, FUMES,
ETC. HAZ DECOMP: PRDCES HYDROGEN CHLORIDE. PHOSGENE . EFTS OF
OVEREXP: INTENTIONAL MISUSE BY DELIB CONC & INHALING CONTENTS MAY
BE HARMFUL/FATAL. CHLOROCARBON MATLS HAVE PRDCD SENSIT OF
MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD (ING 5)

Boiling Pt:B.P. Text:165F,74C
Vapor Pres:100@20C
Vapor Density:4.55
Spec Gravity:1.298@25C
Evaporation Rate & Reference:0.4(BUTYL ACETATE=1)
Solubility in Water:0.07G/100G@25C
Appearance and Odor:COLORLESS LIQUID. IRRITATING ODOR AT HIGH
CONCENTRATIONS.

Stability Indicator/Materials to Avoid:YES
STRONG ALKALIS, OXIDIZING MATERIALS.
Stability Condition to Avoid:HEAT, SPARKS AND OPEN FLAME. DO NOT ALLOW
VAPORS TO ACCUMULATE.
Hazardous Decomposition Products:(INCL COMBUST PROD): FLAMM FUMES MAY
ACCUMULATE IN CONFINED AREA & SPARKS/OPEN FLAMES MAY IGNITE IT.
DECOMP (SUPDAT)

Waste Disposal Methods:(CONTR TYPES, NEUT, ETC). USE METAL CONTR MARKED
"DO NOT REUSE". PUT MATERIAL IN THIS CONTAINER. USE VERMICULITE OR
OTHER INERT ABSORBENT. KEEP AWAY FROM SEWER. NOTE: DISPOSE OF ALL
WASTES I/A/W FEDER AL, STATE AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.